NULLS LAST keyword usage

-> HR.EMPLOYEES will be test table.
SQL> 
DESC HR.EMPLOYEES;

e.g.
To populate all data
SQL> 
SELECT * FROM HR.EMPLOYEES;

To manipulate data by "COMMISSION_PCT" column descending order.
SQL> 
  SELECT *
    FROM HR.EMPLOYEES
ORDER BY COMMISSION_PCT DESC;

-> This is wrong query cause "NULL" columns show on top. Therefore, "NULLS LAST" keyword should be used.
SQL>
  SELECT *
    FROM HR.EMPLOYEES
ORDER BY COMMISSION_PCT DESC NULLS LAST;

SQL PLUS system parameters usage (set/show)

To show parameter in detail
SQL> SHOW DEFINE;

To escape from substitution variable (&):
SQL> SET DEFINE OFF;

To enable DBMS_OUTPUT:
SQL> SET SERVEROUTPUT ON;

To see old and new values of variables:
SQL> SET VERIFY ON;

To calculate total execution time of SQL:
SQL> SET TIMING ON;

To print time on the SQL terminal:
SQL> SET TIME ON;

To see table columns name and types for a table:
SQL> DESC hr.employees@XE;

To see currently logged-in user:
SQL> SHOW user;